The Effects of Magnesium Oxide Nanoparticles Addition on Some Mechanical Properties of Room Temperature Vulcanized Maxillofacial Silicone

Section: Research Paper

Abstract

Aims: This study aimed to assess the effect of incorporating different concentrations of MgO nanoparticles on some mechanical properties of room-temperature vulcanized) RTV) maxillofacial silicone material.


Materials and Methods: A total of 120 silicone specimens were constructed,40 specimens for each mechanical property, which are tear, tensile, and hardness groups, and each group was divided into four subgroups according to MgO Nps concentration (0%, 1%, 2%, and 3%) groups with 10 specimens for each one. Silicone and MgO Nps were mixed and cured according to their standardization procedures. Tear and tensile strength were estimated by utilizing a universal testing machine; Shore A hardness was estimated with a durometer. Fourier transform infrared spectroscopy (FTIR) was used to check the chemical integrity and molecular interactions between silicone and MgO NPs.


Results: One-way ANOVA showed that the addition of MgO NPs significantly changed the mechanical properties of silicone elastomers (p ≤ 0.05). Both tear and tensile strength reached their highest values at 2% MgO Nps, followed by 1% MgO Nps, and then declined at 3% MgO Nps concentration. Post-hoc pairwise comparison reveals no significant difference between the 1% and 3% groups for the tear strength test and no significant difference between the control and 3% groups for tensile strength. Shore A hardness increased as the concentration of MgO NPs increased from 1% to 3%, with a significant difference among all groups. FTIR showed the same peak intensities in the control and experimental groups, indicating that no changes or molecular interactions had occurred.



Conclusion: The incorporation of MgO nanoparticles affected the tested mechanical properties of RTV maxillofacial silicone. The concentration of 2% was considered the ideal percentage of MgO NPs for both tear and tensile strength; higher concentrations further increase surface hardness but reduce the overall material strength parameter.


References

  1. Viswanath S, Sreekumar S, Janakiram C, Nayar S, Mathew A. Treatment outcomes in maxillofacial rehabilitation: a scoping review protocol. JBI Evid Synth. 2024;22(10):2156-2161.
  2. de Caxias FP, dos Santos DM, Bannwart LC, de Moraes Melo Neto CL, Goiato MC. Classification, History, and Future Prospects of Maxillofacial Prosthesis. International Journal of Dentistry. 2019;2019:1-7. doi.org/10.1155/2019/8657619
  3. Mersin TÖ, Kılıçarslan MA, Tetik E. Improvement of speech by facial prosthesis in a midfacial defect with a gunshot injury: A case report. J Prosthodont. 2023;32(7):553-559. DOI: 10.1111/jopr.13693.
  4. Cevik P, Polat S, Duman AN. Effects of the addition of titanium dioxide and silaned silica nanoparticles on the color stability of a maxillofacial silicone elastomer submitted to artificial aging. Cumhur. Dent. J. 2016; 19(1): 9–15. DOI:10.7126/cdj.58140.5000113108
  5. Academy of Prosthodontics. (2017). Glossary of prosthodontic terms. J Prosthet Dent. 117(5S): e56, e86.
  6. Lanzara R, Viswambaran M, and Kumar D. Maxillofacial prosthetic materials: current status and recent advances: A comprehensive review. International Journal of Applied Dental Sciences 2021; 7(2): 255-259. DOI:10.22271/oral.2021.v7.i2d.1219
  7. Mohammed AJ, Alirhayim RN, The Effect of Nanoparticles Addition on the Physical Properties of the Maxillofacial Silicone: A Literature Review, J Res Med Dental Science, 2022; 10(2): 760-764.
  8. Martín C, Kostarelos K, Prato M, Bianco A. Biocompatibility and biodegradability of 2D materials: graphene and beyond. Chemical Communications. 2019;55:5540–5546. https://doi.org/10.1039/C9CC01205B
  9. Gradinariu AI, Racles C, Stoica I, Stelea CG, Simionescu A-MA, Jehac AE, Costan VV. Silicones for Maxillofacial Prostheses and Their Modifications in Service. Materials. 2024; 17(13):3297. doi.org/10.3390/ma17133297
  10. Chen J, Peng H, Wang X, Shao F, Yuan Z, Han H. Graphene oxide exhibits broad- spectrum antimicrobial activity against bacterial phytopathogens and fungal conidia by intertwining and membrane perturbation. Nanoscale. 2014;6(3):1879–1889. doi.org/10.1039/C3NR04941H
  11. Bunyan SF, Suhaimi FM, Zardawi FMM, Noor SNFM, and Zabidi MA. Nanoparticles in enhancing mechanical properties of silicone for maxillofacial rehabilitation - a review. J Evolution Med Dent Sci .2023;12(09):280-285.
  12. Srinivasan VK, Chander NG, Balasubramaniam M. Estimation of graphene oxide nanoparticle reinforcement on the mechanical properties of maxillofacial silicone. Journal of Oral Biology and Craniofacial Research. 2025;15(6):1479-1484. https://doi.org/10.1016/j.jobcr.2025.09.007
  13. Cevik P, Eraslan O. Effects of the addition of titanium dioxide and silaned silica nanoparticles on the mechanical properties of maxillofacial silicones. J Prosthodont. 2017;26(7):611–615. doi.org/10.1111/jopr.12438
  14. Srivastava AK, Pathak VK. Computational insights into nanofiller–matrix interaction region: a review of enhanced mechanical behaviour in nanocomposites. Multiscale and Multidisciplinary Modeling, Experiments and Design. 2026; 9:96. doi.org/10.1007/s41939-026-01180-3
  15. Jwaziri AK, Salavatiha Z, Kiani SJ, Khales P, Vazirzadeh M, Tavakoli A. Magnesium Oxide Nanoparticles: A New Frontier in Antiviral Therapy Against Herpes Simplex Virus Type1.Advances in Virology. 2025;2025:3088529. doi: 10.1155/av/3088529.
  16. . Krishnamoorthy K, Moon JY, Hyun HB, Cho SK, and Kim SJ, “Mechanistic Investigation on the Toxicity of MgO Nanoparticles toward Cancer Cells,” Journal of Materials Chemistry.2012; 22( 47): 24610-24617. DOI:10.1039/c2jm35087d
  17. Soliman MKY, Talib AH, Mahmoud R, et al. Eco-friendly magnesium oxide nanoparticles: anticancer, antimicrobial, and antidiabetic potentials in vitro. AMB Express. 2025;15(1):143. doi: 10.1186/s13568-025-01950-1
  18. Rathika K, Doss PA, Sheela JRAH, Gurunathan V, Kumar KJS, Sathishkumar C, Thirumal V, Kim J. Comparative Evaluation of Antioxidant and Antidiabetic Activities of ZrO2 and MgO Nanoparticles Biosynthesized from Unripe Solanum trilobatum Fruits: Insights from In Vitro and In Silico Studies. Nanomaterials. 2025; 15(17):1372. https://doi.org/10.3390/nano15171372
  19. El-Khatib AM, Gouda MM, Fouad MS, Abd-Elzaher M, Ramadan W. Radiation attenuation properties of chemically prepared MgO nanoparticles/HDPE composites. Sci Rep. 2023;13(1):9945. doi: 10.1038/s41598-023-37088-y
  20. Samad A, Lau KY, Khan IA, Khoja AH, Jaffar MM, and Tahir M. Structure and breakdown property relationship of polyethylene nanocomposites containing laboratory-synthesized alumina, magnesia, and magnesium aluminate nanofillers. Journal of Physics and Chemistry of Solids. 2018; 120: 140–146. https://doi.org/10.1016/j.jpcs.2018.04.036
  21. . Hegde, V.N, Manju, V, Pradeep, TM and Sandhya, N. Structural, Morphological, Elastic, Optical and Electrical properties of MgO nanostructures. Materials Chemistry and Physics. 2024; 322: 129518. doi.org/10.1016/j.matchemphys.2024.129518
  22. . Kumari S, Mishra RK, Parveen S, Avinashi SK, Hussain A., Kumar S, Banerjee M, Rao J, Kumar R, Gauta RK, and Gautam C. Fabrication, structural, and enhanced mechanical behavior of MgO substituted PMMA composites for dental applications. Scientific reports. 2024; 14(1): 2128. doi: 10.1038/s41598-024-52202-4
  23. Gatou, MA, Skylla E, Dourou P, Pippa N, Gazoul M, Lagopati N and Pavlatou EA. Magnesium Oxide (MgO) Nanoparticles: Synthetic Strategies and Biomedical Applications. Crystals. 2024;14: 215. doi.org/10.3390/cryst14030215
  24. Abdel-Aziz MM, Emam TM, Elsherbiny EA. Bioactivity of magnesium oxide nanoparticles synthesized from the cell filtrate of endobacterium Burkholderia rinojensis against Fusarium oxysporum. Materials Science & Engineering C. 2020;109:110617. DOI:10.1016/j.msec.2019.110617
  25. Hussein IE. Hasan RH. Effects of Nano Zirconium Oxide Addition on the Strength, Hardness, and Microstructure of Maxillofacial Silicone Material. International Medical Journal.2021;28(1): 54 – 57. doi: 202102266668784750
  26. Shakir DA, Abdul-Ameer FM. Effect of nano-titanium oxide addition on some mechanical properties of silicone elastomers for maxillofacial prostheses. J Taibah Univ MedSci. 2018; 13: 281-290.
  27. ISO 23529, Standardization, Rubber-General procedures for preparing & conditioning test pieces for physical test methods; (2016).
  28. Abdalqadir M, Faraj S, Azhdar B. An evaluation of a technique to improve the mechanical properties of maxillofacial silicone elastomers with zinc oxide nanoparticles. The Journal of Prosthetic Dentistry. 2021; 128: 531-538. doi.org/10.1016/j.prosdent.2020.09.043
  29. ASTM D624-00. Standard Test Method for Tear Strength of Conventional Vulcanized Rubber & Thermoplastic Elastomers. ASTM International, West Conshohocken, PA, USA; 2020.
  30. ISO 37, Rubber, vulcanized or thermoplastic-Determination of tensile stress-strain properties; (2017).
  31. ASTM D2240-15 International. Standard Test Method for Rubber Property—Durometer Hardness, West Conshohocken, 2021.
  32. Bahl, A, Bahl BS.A Textbook of Organic Chemistry. 22nd Edn. S.Chand and Company. (2019), India.
  33. Rahman AM, Jamayet NB, Nizami M, Johari Y. Effect of Aging and Weathering on the Physical Properties of Maxillofacial Silicone Elastomers: A Systematic Review and Meta-Analysis. J Prosthodont 2019; 28: 36-48. DOI:10.1111/jopr.12950.
  34. Anusavice, KJ, Shen, C, Rawls, HR. Phillips' Science of Dental Materials. 12th Edn. Elsevier Saunders. (2013), USA; Pp 164.
  35. Abdul-Ameer FM. Impact of a mixture of nanofiller and intrinsic pigment on tear strength and hardness of two types of maxillofacial silicone elastomers. Dental research journal.2020; 17(4):251–257.
  36. Sun L, Gibson RF, Gordaninejad F, and Suhr J. Energy absorption capability of nanocomposites: A review, Comp Sci Tech. 2009;69(14): 2392-2409. doi.org/10.1016/j.compscitech.2009.06.020
  37. Haider YM, Abdullah ZS, Fatalla AA, Jani GH, and Mokhtar N. “Corrigendum to “evaluation of some mechanical polyester powder, International Journal of Dentistry. 2019;2019(3). doi: 10.1155/2020/7187159
  38. Academy of Prosthodontics. (2017). Glossary of prosthodontic terms. J Prosthet Dent. 117 (2017) e1–e105.
  39. Sakaguchi R, Ferracane J, and Powers JM. Craig’s Restorative Dental Materials. 14th ed.St Louis, MO: Elsevier/Mosby;2019.
  40. Tukmachi MS, Safi IN, Ali MM: Evaluation of mechanical properties and cytotoxicity of maxillofacial silicone material after incorporation of zirconia nanopowder.Mater. Today: Proc.2021;42:2209–2217.https://doi.org/10.1016/j.matpr.2020.12.306
  41. Bunyan FS, Suhaimi MF, Zardawi FMM, Mohd Noor SNF, Zabidi MA. Enhancement of Tech-Sil25 Maxillofacial Silicone Mechanical Properties after Artificial Weathering through Addition of Nanoparticles. Int J Dent. 2022;2022:4082168. doi.org/10.1155/2022/4082168
  42. Hatamleh MM, Watts DC. Mechanical properties and bonding of maxillofacial silicone elastomers. Dental Materials. 2010;26(2):185-91. https://doi.org/10.1016/j.dental.2009.10.001
  43. Yamada, C., Yasumoto, A., and Blume, A. Influence of the number of end-chain amine-functionalized arms of star-shaped functionalized SBR. Polym. Bull. 2024;81: 11049–11075 .doi.org/10.1007/s00289-024-05160-w
  44. Bokobza L. Elastomer Nanocomposites: Effect of Filler-Matrix and Filler-Filler Interactions. Polymers (Basel). 2023;15(13):2900. https://doi.org/10.3390/polym15132900
  45. Anjali A, Chethan H. Effects of incorporation of nanoparticles on the mechanical properties of maxillofacial silicone elastomer subjected to outdoor weathering. Heliyon. 2024;21:10(3):e25039. https://doi.org/10.1016/j.heliyon.2024.e25039
  46. Han Y, Kiat-amnuay S, Powers JM, Zhao Y. Effect of nano-oxide concentration on the mechanical properties of a maxillofacial silicone elastomer. J Prosthet Dent. 2008;100(6):465-473. doi.org/10.1016/S0022-3913(08)60266-8
  47. Al-Samaray, ME, Al-Somaiday, HM, and Rafeeq, AK. Effect of Adding Different Concentrations of CaCO3-SiO2 Nanoparticles on Tear Strength and Hardness of Maxillofacial Silicone Elastomers. Nano Biomedicine and Engineering.2021; 13(3): 257-263. DOI:10.5101/nbe.v13i3.p257-263.
  48. Ahmed AS, Ali MM: Effect of Strontium Titanate Nano Powder Addition on Some Mechanical Properties of Room Temperature Vulcanized Maxillofacial Silicone. Journal of Research in Medical and Dental Science. 2021;9(12): 59–65.
  49. Khanna M, Sehgal K, Singla S, Kumar V. Effect of Organic and Inorganic Nanoparticles on Colour Stability and Mechanical Properties of Heat Vulcanised Maxillofacial Silicone Elastomer: a Comparative Study. J Oral Maxillofac Res. 2024;15(1):e4.

Identifiers

Download this PDF file
##submission.supplementaryFiles##

Statistics

Copyright and Licensing